(2-Decanamidoethyl)dimethylamine N-oxide
نویسنده
چکیده
In the title compound, C(14)H(30)N(2)O(2), the almost planar nonyl chains are fully extended: the N-C-C-N torsion angle of -161.95 (8)° indicates an anti conformation. The crystal structure features N-H⋯O hydrogen bonds and C-H⋯O inter-actions.
منابع مشابه
Dibromidotris(dimethylamine)magnesium(II)
The Mg centre in the title compound, [MgBr(2)(C(2)H(7)N)(3)], is penta-coordinated in a trigonal-bipyramidal mode with the two Br atoms in axial positions and the N atoms of the dimethyl-amine ligands in equatorial positions. The Mg(II) centre is located on a crystallographic twofold rotation axis. The crystal structure is stabilized by N-H⋯Br hydrogen bonds. The N atom and H atoms of one dimet...
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The reaction of diphenylcyclopropenone with several N-substituted hydroxylamine and primary amines are investigated. Most of these reactions led to ring opened or ring enlarged products, instead of the desired N-Oxide or imine. The reaction of cyclopropeneimine with peracid-another possible route to N-substituted cyclopropeneimine N-Oxide is studied. Most of the unexpected products are ide...
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N-Oxidation of 1,4-dihydro-2,6-dimethyl-1- phenyliminopyridine (7) with several peracids was attempted. The main compound obtained was l-phenyl- 2,6-dimethyl-4-pyridone (8), instead of the expected N-oxide (2). The reaction of phenylhydroxylamine with dimthylrnethoxypyroxonium perchlorate, however, successfully gave the N-oxide (3), which belongs to a class of nitrones in which the diazomet...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010